Fully Delocalized (Ethynyl)(vinyl)phenylene-Bridged Diruthenium Radical Complexes
نویسندگان
چکیده
Florian Pevny, Emmanuel Di Piazza, Lucie Norel, Malte Drescher, Rainer F. Winter,* and St ephane Rigaut* Institut f€ ur Anorganische Chemie der Universit€ at Regensburg, Universit€ atsstrasse 31, D-93040 Regensburg, Germany, Fachbereich Chemie der Universit€ at Konstanz, Universit€ atsstrasse 10, D-78453 Konstanz, Germany, and UMR 6226 CNRS-Universit e de Rennes 1, Sciences Chimiques de Rennes, Campus de Beaulieu, F-35042, Rennes Cedex, France
منابع مشابه
Ruthenium stilbenyl and diruthenium distyrylethene complexes: aspects of electron delocalization and electrocatalyzed isomerization of the Z-isomer.
Regio- and stereoselective insertion of the terminal ethynyl functions of 4-ethynylstilbene, the E and Z isomers of 4,4'-bis(ethynylphenyl)ethene and a backbone-rigidified cyclohexenyl derivative of the Z isomer into the Ru-H bond of the complex RuClH(CO)(P(i)Pr(3))(2) provides the corresponding vinyl ruthenium complexes, which have been characterized spectroscopically and by X-ray crystallogra...
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